Process for forming ethers

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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560 61, 560 64, 568584, 568585, 568586, 568630, 568631, 568636, 568639, 568644, 568645, 568648, C07C12175, C07C 4101, C07C 7935

Patent

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043494870

ABSTRACT:
Phenolic compounds are etherified by contacting at elevated temperature with a mixture of methyl trichloroacetate and either a primary alkyl halide or an aromatic halide containing strongly electron-withdrawing groups in the presence of an initiator.

REFERENCES:
B. Smith, Acta Chem. Scand., 10, 1006, (1956).
E. E. Smissman et al., J. Org. Chem., 37, 3944, (1972).
E. Vowinkel, Chem. Ber., 99, 1479, (1966).
S. Bittner et al., Chem. and Ind., 281, (1975).

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