Porphyrins and metal complexes thereof having haloalkyl side cha

Details Porphyrins and metal complexes thereof having haloalkyl side cha Porphyrins and metal complexes thereof having haloalkyl side cha

1995-03-17

1997-03-04

Datlow, Philip I.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

C07D48722

Patent

active

056080549

ABSTRACT:
Transition metal complexes of meso-haloalkylporphyrins, wherein the haloalkyl groups contain 2 to 8 carbon atoms have been found to be highly effective catalysts for oxidation of alkanes and for the decomposition of hydroperoxides.

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DiMagno et al., "Facile Synthesis of meso-tetrakis(perfluoroalkyl) porphyrins: Spectroscopic Properties and X-Ray Crystal Structure of Highly Electron-Deficient 5,10,15,20-Tetrakis(Heptafluoropropyl) Prophyrin." J. Organ. Chem., 59, 23, 6943-6948 (1994).
R. W. Wagner et al., "Building Block Synthesis of Linear-Amphipathic Porphyrin Arrays", Meeting of Amer. Chem. Soc. Div. Org. Chem., Mar. 13-17, 1994, San Diego, CA (poster abstract and paper).
DiMagno et al, Chem. Abstract 1995:699361 (1995) with attached STN printout.
Lee et al., Chem. Abstract 122:187202 (1995) with STN printout.

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