Liquid metal cathode electrochemical cell

Chemistry: electrical and wave energy – Apparatus – Electrolytic

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204279, C25B 900, C25B 1508

Patent

active

051868040

ABSTRACT:
A particular side frame design for use in an electromechanical cell with a catholyte flow pattern is disclosed wherein the cell is angled from the horizontal and the catholyte is fed into a gap in the cathode compartment between the liquid metal cathode and the membrane on the lower first end and exits the gap on the opposing higher second outlet end. The side frame is obliquely angled on the interior of the cell to prevent the escape of the flowable liquid metal cathode and to prevent contact of the acidic catholyte with the cell bottom.

REFERENCES:
patent: 727025 (1903-05-01), Tafel
patent: 2242477 (1941-05-01), Osswald et al.
patent: 4036714 (1977-07-01), Spitzer
patent: 4101407 (1978-07-01), Hilare et al.
patent: 4556470 (1985-12-01), Samejima et al.
patent: 4586994 (1986-05-01), Samejima et al.
patent: 4596639 (1986-06-01), Nishio et al.
patent: 4849073 (1989-07-01), Dotson et al.
Article entitled "Hydroxylamine Production by Electroreduction of Nitric Oxide in a Trickle Bed"-The Canadian Journal of Chemical Engineering, vol. 57, Oct., 1979.

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