Preparation of 1,4-butanediol

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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C07C 2700

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059774177

ABSTRACT:
1,4-Butanediol is prepared by a process which comprises converting 1,3-butadiene diepoxide in the presence of hydrogen over a hydrogenation catalyst whose active component is not elemental Pd and/or Pt. The hydrogenation catalyst preferably contains at least one element from the group Ib, VIIb or VIIIb of the Periodic Table of Elements.

REFERENCES:
J. Org. Chem., 1984, 49, pp. 3707-3711.
Houben-Weyl: Methoden der Organischen Chemie, VI/3, pp. 435-441.
Ullmann's Encyclopedia of Industrial Chemistry, 5th Ed., vol. A26, p. 222.
Weissermel-Arpe: Industrielle Organische Chemie, 4, p. 112.

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