Process for dimerizing acrylates and methacrylates

Details Process for dimerizing acrylates and methacrylates Process for dimerizing acrylates and methacrylates

1985-09-12

1987-01-20

Trousof, Natalie

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

502102, 562590, 562592, C07C 67343

Patent

active

046380841

ABSTRACT:
A process is disclosed for dimerizing lower alkyl acrylates or lower alkyl methacrylates utilizing a bis(ethylene) rhodium tetrafluoroborate catalyst.

REFERENCES:
patent: 3013066 (1961-12-01), Alderson
patent: 3560561 (1971-02-01), Scheben et al.
patent: 4451665 (1984-05-01), Nugent
Oehne & Pracejus, Tetrahedron Letters, No. 4, pp. 343-348, 1979.
Alderson et al, J. Am. Chem. Soc., 87, pp. 5638-5645, 1965.

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