Aminomethanobenzazocine intermediates

Details Aminomethanobenzazocine intermediates Aminomethanobenzazocine intermediates

1977-08-22

1979-03-20

Trousof, Natalie

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

424267, C07D22126

Patent

active

RE0299430

ABSTRACT:
N-Alkylated-8-aminated-2,6-methano-3-benzazocines, useful as strong analgesics, are prepared by one route comprising reduction of 8-nitro intermediates or by another route comprising Birch type reduction of 8-methoxy intermediates followed by dehydration-rearrangement of the oximes of the resulting 8-oxo intermediates.

REFERENCES:
patent: 3632591 (1972-01-01), Albertson et al.
patent: 3764606 (1973-10-01), Akkerman et al.
patent: 3853889 (1974-12-01), Monkovic et al.
patent: 4009171 (1977-02-01), Albertson

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