Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1970-12-22
1976-02-03
Brust, Joseph P.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
260465R, 260465C, 2604658R, 2604659, 260540, 260586R, 260593R, 260617R, 260668F, 260677R, C07C12000
Patent
active
039364909
ABSTRACT:
Process for reacting organonitriles with hydrocarbon substrates, by contacting with a basic alkali metal catalyst in a solvent selected from the group consisting of trimethyl phosphoramide, hexamethyl phosphoramide, tetramethyl urea and N-methyl-2-pyrollidone.
REFERENCES:
patent: 2971024 (1961-02-01), Zaugg et al.
pearson, et al., J.A.C.S., 75 (1953), pp. 2439-2443.
Rappoport, The Chemistry of the Cyano Group, 1970, pp. 125-127.
Kosower, Physical Organic Chemistry, 1968, pp. 21-41.
Hofmann John E.
Schriesheim Alan
Baran Robert J.
Brust Joseph P.
Exxon Research and Engineering Company
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