Process for converting thallium (I) to thallium (III)

Details Process for converting thallium (I) to thallium (III) Process for converting thallium (I) to thallium (III)

1976-11-08

1978-09-19

Sneed, Helen M. S.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

423395, 423495, 423544, 423659, C07F 500

Patent

active

041154215

ABSTRACT:
A monovalent thallium compound is converted to a trivalent thallium compound by treating the thallium (I) compound with an organic hydroperoxide in the presence of a Group VIII noble metal catalyst in a liquid medium to oxidize the thallium (I) compound to a thallium (III) compound.

REFERENCES:
patent: 3399956 (1968-09-01), Hirose et al.
patent: 3436409 (1969-04-01), Hill et al.
patent: 3479262 (1969-11-01), MacLean et al.
patent: 3792069 (1974-02-01), Baird et al.
patent: 3816540 (1974-06-01), Barone et al.
Spencer, L., Anorg. Chem., vol. 44, pp. 379-399 (1905).
Spencer, L., Anorg. Chem., vol. 44, pp. 399-407 (1905).
Spiro et al., J. Chem. Soc., pp. 78 to 96 (1965).
Chemical Abstracts, 64, 13800h (1966).
Chemical Abstracts, 67, 96732e (1967).
Chemical Abstracts, 63, 1471a (1965).
Chemical Abstracts, 73, 47165e (1970).

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