Use of electrocatalytic anodes in photolysis

Chemistry: electrical and wave energy – Processes and products – Electrostatic field or electrical discharge

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204129, 204290R, 204290F, 204291, 204292, 204252, 2041571R, 429111, C25B 104, C25B 126, C25B 1108, C25B 1110

Patent

active

043892906

ABSTRACT:
A photolytic system comprised of a darkened halfcell and an illuminated halfcell in which oxidation and reduction reactions are made to occur. These halfcells are joined by an electrically conductive element and an ion conducting junction for electron transfer and ion transport. The illuminated halfcell is equipped with a cathode and the darkened halfcell contains an improved anode which exhibits a desirably low overvoltage with respect to the substrate which is sought to be oxidized. Oxidation products are formed at the anode and reduction products are formed at the cathode.

REFERENCES:
patent: 4011149 (1977-03-01), Nozik
patent: 4090933 (1978-05-01), Nozik
"O.sub.2 Generated from H.sub.2 O Photochemically", C & EN, Jul. 23, 1979, pp. 24-25.

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