Process for the selective hydrogenation of epoxyalkenes to epoxy

Details Process for the selective hydrogenation of epoxyalkenes to epoxy Process for the selective hydrogenation of epoxyalkenes to epoxy

1994-09-23

1996-03-12

Gibson, Sharon

Catalyst, solid sorbent, or support therefor: product or process

Catalyst or precursor therefor

Organic compound containing

502166, 585277, 585275, B01J 3100

Patent

active

054985846

ABSTRACT:
Disclosed in a process for the homogeneous, catalytic hydrogenation of epoxyalkenes and epoxycyclo-alkenes, especially conjugated .gamma.,.delta.-epoxyalkenes and epoxycycloalkenes, to the corresponding epoxyalkanes and epoxycycloalkanes using a solution of a complex rhodium catalyst whereby the olefinic unsaturation is hydrogenated without significant hydrogenolysis of the conjugated epoxy group.

REFERENCES:
patent: 4743699 (1988-05-01), Page et al.
patent: 4863639 (1989-09-01), Heggie et al.
patent: 4999443 (1991-03-01), Bertleff et al.
patent: 5334791 (1994-08-01), Cavell et al.
Schrock, R. R. et al, J.A.C.S. 93:10, pp. 2397-2407, 1971 (I).
Schrock, R. R. et al., J.A.C.S. 98:8, pp. 2143-2147, 1976 (II).
Fujitsu, H., et al., J.A.C.S., Perkin I, 855-859, 1982.
Crabtree, R. H., et al., J. Organometallic Chemistry, 141, pp. 113-121, 1977.
Landis, C. R., et al., J. Organometallic Chemistry, 250 pp. 485-490, 1983.

Affiliated with

Also associated with

Rating

Process for the selective hydrogenation of epoxyalkenes to epoxy does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Process for the selective hydrogenation of epoxyalkenes to epoxy, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Process for the selective hydrogenation of epoxyalkenes to epoxy will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-2099872