Process for removing carbon dioxide containing acidic gases from

Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Carbon dioxide or hydrogen sulfide component

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423236, 423243, B01D 5334

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active

041120523

ABSTRACT:
Carbon dioxide containing acidic gases are substantially removed from a normally gaseous mixture by a process comprising contacting the normally gaseous mixture with an aqueous amine solution, wherein at least one of the amines is a sterically hindered amine. The process is operated at a thermodynamic cyclic capacity (as determined from the vapor liquid equilibrium isotherm of the vapor-liquid system) which is greater than in an aqueous amine CO.sub.2 scrubbing process wherein monoethanolamine is the only amine utilized under similar conditions of gaseous feed composition, scrubbing solution composition, temperatures and pressures. A particularly preferred sterically hindered amine is 2-amino-2-methyl-1-propanol.

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