Organoaluminum-organophosphine-metal salt of a beta-diketone cat

Compositions – Preservative agents – Anti-oxidants or chemical change inhibitants

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526187, 526188, 526189, 528416, 526 476, 526 481, B01J 3112, B01J 3114

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active

041168690

ABSTRACT:
A catalyst system comprising (I) an organoaluminum compound, (II) an organophosphine compound, and (III) a metal salt of a beta-diketone, is effective to homopolymerize an alkene oxide, homopolymerize an ester of acrylic or methacrylic acid or certain other vinyl monomers, or to copolymerize an alkene oxide with an ester of acrylic or methacrylic acid or certain other vinyl monomers. Suitable vinyl monomers include vinyl esters, vinyl ethers, or vinyl ketones.

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patent: 3798285 (1974-03-01), Yoo et al.
patent: 3925317 (1975-12-01), Hsieh
patent: 4020018 (1977-04-01), Hsieh

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