Process for preparing low unsaturation polyether polyols

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

Patent

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

568619, 568620, 568621, 568623, 568624, C07C 4144

Patent

active

056987463

ABSTRACT:
Polyether polyols having reduced terminal unsaturation are prepared in a process comprising a first step of contacting a polyether having allyl terminal unsaturation with an isomerization catalyst whereby the allyl terminal unsaturation of the polyether is reduced by at least 90% conversion to propenyl terminal unsaturation in one step and, in a final step, the resulting polyether product of the first step is contacted with an acid catalyst whereby a substantial amount of the propenyl terminal unsaturation of the polyether is removed and the corresponding polyether having an additional hydroxyl group is obtained.

REFERENCES:
patent: 2996550 (1961-08-01), Simons
patent: 3117998 (1964-01-01), Cosby et al.
patent: 4029879 (1977-06-01), Muzzio
patent: 5010187 (1991-04-01), Heuvelsland
patent: 5070125 (1991-12-01), Heuvelsland
patent: 5095061 (1992-03-01), Chavez, Jr. et al.
patent: 5102428 (1992-04-01), Owen et al.
patent: 5103042 (1992-04-01), Durvasula et al.
patent: 5288924 (1994-02-01), Beech, Jr. et al.
patent: 5342541 (1994-08-01), Chavez, Jr. et al.
A. Stolarzewicz, et al., "Zur Ubertragungsreaktion bei der Anionschen Polymerisation von Oxiranen I. Zum Einfluss des Initiatorsystems auf die Kettenubertragung," Acta Polymerica, vol. 32, No. 8, 1981, pp. 483-486. (and translation).
H. Becker, et al., "Zur Ubertragungsreaktion bei der Anionschen Polymerisation von Oxiranen III. Zum Dynamik der Doppelbindungsbildung bei der Propylenoxidpolymerisation," Acta Polymerica, vol. 33, No. 1, 1982, pp. 34-37. (and translation).
H. Becker, et al., "Zur Ubertragungsreaktion bei der Anionschen Polymerisation von Oxiranen IV. Zum Einfluss von Kronenetherzusatzen auf die Polymerisation von Propylenoxid," Acta Polymerica, vol. 35, No. 1, 1984, pp. 28-32. (and translation).
J. Ding, et al., "Use of Crown Ether in the Anionic Polymerization of Propylene Oxide--2. Molecular Weight and Molecular Weight Distribution," Eur. Polym. J., vol. 27, No. 9, 1991, pp. 895-899.
Derwent Abstract A25 94-001294/01 to EP 576132-A1.
N. Barksby, "Optimizing Properties of Urethane Sealants," Adhesives & Sealants Industry, Jun./Jul., 1994, pp. 38-42.
G.J. Dege et al., "Terminal Unsaturation in Polypropylene Glycol", J.Am.Chem.Soc., 81, pp.3374-3379 (1959).

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Process for preparing low unsaturation polyether polyols does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Process for preparing low unsaturation polyether polyols, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Process for preparing low unsaturation polyether polyols will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-208138

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.