Process for producing biphenyltetracarboxylic dianhydrides

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260515P, 260524R, 260524N, C07D30789

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active

039404269

ABSTRACT:
A process for separating and purifying biphenyltetracarboxylic dianhdride isomers from a mixture of these isomers by fractional crystallization in aliphatic acid anhydrides or acetone. The isomeric mixture is obtained by heating biphenyltetracarboxylic acids, optionally in the presence of an aliphatic acid anhydride. The biphenyltetracarboxylic acids are obtained by oxidizing coupling dimers of o-xylene or by hydrolyzing coupling dimers of dimethyl phthalate.

REFERENCES:
patent: 3173947 (1965-03-01), Essen et al.
patent: 3179614 (1965-04-01), Edwards
patent: 3338923 (1967-08-01), Peterlein et al.
patent: R27296 (1972-02-01), Ichikawa et al.
Ichikawa et al., C. A., Vol. 74, 126336k.
Groggins, "Unit Processes Inorganic Synthesis," 4 edition, 1952, p. 658.

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