Process for the preparation of naphthalene-1,3,6-trisulphonic ac

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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C07C14330

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041805216

ABSTRACT:
A process has been invented for the preparation of naphthalene-1,3,6-trisulphonic acid by sulphonating naphthalene with sulphuric acid and oleum, characterized in that naphthalene and most of the oleum are simultaneously metered into sulphuric acid or oleum of low concentration, which has been initially introduced, at about 140.degree. to 240.degree. C., the temperature is kept at about 140.degree. to 240.degree. C. for some time, the remainder of the oleum is then added at about 140.degree. to 240.degree. C. and the mixture is then further stirred for some time.
Naphthalene-1,3,6-trisulphonic acid is a known important intermediate used, for example, in the preparation of T-acid, H-acid and chromotropic acid.

REFERENCES:
patent: 1311090 (1919-07-01), Pratt et al.

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