Process for the preparation and uses of derivatives of esters of

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

Patent

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

549206, 560 61, 560 62, 560 83, 560212, 560226, 562599, C07C 6730

Patent

active

061472514

ABSTRACT:
A process for the preparation of derivatives of halo-but-2-enoic acids and esters high in 2-ene content, several of which are novel. The esters and their derivatives are useful as promoters for the polymerization of ethylene or the copolymerization of ethylene with .alpha.-olefins and, optionally, nonconjugated polyenes. The promoters can also be combined with transition metal compounds, e.g., vanadium, to form combination promoter-catalyst compounds.

REFERENCES:
patent: 2515306 (1950-07-01), Ladd et al.
patent: 3260708 (1966-07-01), Natta et al.
patent: 3743669 (1973-07-01), Hillman et al.
patent: 4189558 (1980-02-01), Witte et al.
patent: 4378455 (1983-03-01), Kawasaki et al.
patent: 5527951 (1996-06-01), Khan et al.
Kimura et al., Polymer J., vol. 15, No. 4, pp. 293-301; 1983.
Benincasa et al., "Reductive Homo-Coupling of Methyl 2-Br-2-Cl-Carboxylates Promoted by CuBr-Fe," Tetrahedron Letters 36(7):1103-1106 (1995).
Hill, J. et al., "Functionalisation of the .mu. Position of Acrylate Systems By the Addition of Carbonyl Compounds: Highly Pressure-Dependent Reactions," Tetrahedron Letters 27(41):5007-5010 (1986).
Hoffmann et al., "Preparation of 2-(1-Hydroxyalkyl)acrylic Esters; Simple Three-Step Synthesis of Mikanecic Acid," Angew. Chem. Int. Ed. Engl. 22(10):795 (1983).
Rabe et al., "A New, efficient and Stereocontrolled Synthesis of Trisubstituted Alkenes via Functionalized Acrylic Esters," Angew. Chem. Int. Ed. Engl. 22(10):796-7 (1983).
Brown et al., "Organic Syntheses," 68:64 (1989).
J. Chem. Soc. Chem. Comm. 277-278 (1998).
McFadden et al. "Potential Inhibitors of Phosphoenolpyruvate Carboxylase II. Phosphonic Acid Substrate Analogues Derived from Reaction of Trialkyl Phosphites with Halometharcrylates" appearing in Australian Journal of Chemistry, at pages 301-314. Vol, 42 (1989).

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Process for the preparation and uses of derivatives of esters of does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Process for the preparation and uses of derivatives of esters of, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Process for the preparation and uses of derivatives of esters of will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-2066851

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.