Process for selective formation of C.sub.4 compounds and tertiar

Details Process for selective formation of C.sub.4 compounds and tertiar Process for selective formation of C.sub.4 compounds and tertiar

1980-12-11

1982-07-13

Lone, Werren B.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568888, 568902, C07C 2722, C07C 4550

Patent

active

043396089

ABSTRACT:
A process and catalyst system for selectively producing n-butanol and n-butanal which process comprises introducing into a reaction zone methanol, hydrogen, carbon monoxide and a catalyst system consisting essentially of (a) a cobalt carbonyl, a hydrido cobalt carbonyl or a cobalt-containing material convertible to a cobalt carbonyl or a hydrido cobalt carbonyl, (b) an iodine compound and (c) a tertiary organo Group VA compound and then subjecting the contents of said reaction zone to an elevated temperature and an elevated pressure for a time sufficient to convert methanol to n-butanol and n-butanal.

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patent: 4190729 (1980-02-01), Forster
patent: 4205190 (1980-05-01), Gane et al.
patent: 4262154 (1981-04-01), Gane et al.

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