Semisuspension polymerization processes

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526 65, 526 86, 526 88, 526263, 5263031, 5263077, 526316, 5263171, 526328, 5263297, 526334, 526342, 526345, 526346, C08F 202, C08F 216

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058521402

ABSTRACT:
Disclosed is a process for the preparation of a polymer which comprises effecting bulk polymerization of a mixture of at least one monomer, a free radical polymerization initiator, and a stable free radical agent until from about 10 to about 50 weight percent of the monomer has been polymerized; optionally adding additional free radical initiator; optionally adding a colorant; dispersing with a high shear mixer the aforementioned partially polymerized mixture in water containing a stabilizing component selected from the group consisting of non-ionic and ionic water soluble polymeric stabilizers to obtain a suspension of particles with an average diameter of from about 0.1 to about 10 microns; polymerizing the resulting suspension to form said polymer.

REFERENCES:
patent: 5043404 (1991-08-01), Mahabadi et al.
patent: 5164282 (1992-11-01), Mahabadi

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