Method for the interseparation of platinum group metals

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Platinum group metal

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423 24, 423DIG14, 210635, 210656, 210688, 75101BF, 75118R, 75121, C22B 1104

Patent

active

048851434

ABSTRACT:
A method for the interseparation of platinum-group noble metals (PGMs) from a gold-free halide solution using at least one chromatographic column. The solution is passed through a column containing a solid absorbent having a Kd above 1 whereby the PGMs are absorbed. The loaded absorbent is eluted by a halide salt solution obtaining thereby well-spaced fractions, each containing only one single noble metal, coming out in the order: Ru, Rh, Pd, Pt, Ir and Cs. When gold is present with the PGMs, its prior removal is required by an additional chromatographic column containing an absorbent based on polystyrene divinyl.

REFERENCES:
patent: 2714555 (1955-08-01), Stevenson et al.
patent: 3970553 (1976-07-01), Terajima et al.

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