Production of glycidyl compounds

Details Production of glycidyl compounds Production of glycidyl compounds

1991-12-11

1993-09-14

Evans, Joseph E.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

549521, C07D30128, C07D30304, C07D30332

Patent

active

052450481

ABSTRACT:
A process for the production of a glycidyl ether of an alcohol, comprising reacting an alcohol with epichlorohydrin, in substantially the stoichiometric proportions required to produce the 1:1 adduct, in the presence, as catalyst, of a salt of perchloric acid or trifluoromethane sulphonic acid with a metal of Group IIIA of the Periodic Table of Elements (according to the IUPAC 1970 convention); and then dehydrochlorinating the product so obtained.

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patent: 4110354 (1978-08-01), Bertram et al.
patent: 4778863 (1988-10-01), Wang et al.
Houben-Weyl, Methoden Der Organischen Chemie, vol. XIV/2, No. 2, 1963, pp. 475-477.
Houben-Weyl, Methoden Der Organischen Chemie, vol. 20E, 1987; pp. 1911-1924, "Makromolekulare Stoffe" the Journal of Organic Chemistry, vol. 52, No. 6, 1987, pp. 1017-1021.
Tetrahedron, vol. 42, No. 24, 1986, pp. 6573-6614.

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