Transvinylation reaction

Details Transvinylation reaction Transvinylation reaction

1988-06-30

1991-01-01

Wax, Robert A.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

560176, 560217, 585639, 585640, C07C 4105, C07C 6702

Patent

active

049819739

ABSTRACT:
A process for the transvinylation of a vinyl derivative of a Bronsted acid with a different Bronsted acid which comprises providing a liquid phase mixture containing said vinyl derivative and said Bronsted acid in the presence of a ruthenium compound at a temperature at which transvinylation occurs and recovering as a product of transvinylation the vinyl derivative of the different Bronsted acid. The process is most favorably employed using carboxylic acids to make vinyl esters of carboxylic acids.

REFERENCES:
patent: Re27663 (1973-06-01), Fernholtz et al.
patent: 827718 (1960-02-01), Mayne et al.
patent: 877103 (1961-09-01), Mayne et al.
patent: 2245131 (0000-01-01), Herrmann et al.
patent: 2299862 (1942-10-01), Toussaint et al.
patent: 2989554 (1961-06-01), Mayne et al.
patent: 2997494 (1961-08-01), Brown
patent: 3000918 (1961-09-01), Wilip et al.
patent: 3117145 (1964-01-01), Ehrreich
patent: 3158633 (1964-11-01), Port et al.
patent: 3179641 (1965-04-01), Brown et al.
patent: 3188319 (1965-06-01), Smidt et al.
patent: 3201357 (1965-08-01), Fang
patent: 3337611 (1967-08-01), Beardon, Jr.
patent: 3391130 (1968-07-01), Bolstad et al.
patent: 3454644 (1969-07-01), Dewhirst
patent: 3560534 (1971-02-01), MacDonald
patent: 3647832 (1972-03-01), Chabardes et al.
patent: 3725305 (1973-04-01), Wilkinson
patent: 3751449 (1973-08-01), Gobran et al.
patent: 3755387 (1973-08-01), Young
patent: 3786102 (1974-01-01), Godfrey
patent: 3793355 (1974-02-01), Wilkinson
patent: 3965155 (1976-06-01), Smith et al.
patent: 3965156 (1976-06-01), Smith et al.
patent: 4112235 (1978-09-01), Schmerling
patent: 4175056 (1979-11-01), Antos
patent: 4415499 (1983-11-01), Blum et al.
patent: 4424359 (1984-01-01), Kaschig
patent: 4446073 (1984-05-01), Qualeatti et al.
patent: 4458088 (1984-07-01), Hardman
patent: 4640802 (1987-02-01), Drent
patent: 4647691 (1987-03-01), Lin
patent: 4658053 (1987-04-01), Green
patent: 4664851 (1987-05-01), Drent
patent: 4731467 (1988-03-01), Drent et al.
Sandler, S. R., Journal of Chemical and Engineering Data, vol. 14, No. 4, Oct. 1966, pp. 503-506.
Slinckx, G. and Smets, G., Tetrahedron, vol. 22, 1966, pp. 3163-3171.
Hopff, H. and Osman, Maged A., Tetrahedron, vol. 24, 1968, pp. 3887-3890.
Adelman, R. L. Journal Organic Chemistry, 14, 1949, pp. 1057-1077.
Henry, P. M., Accounts of Chemical Research, vol. 6, 1973, pp. 16-24.
Sabel, A. et al., Chem. Ber. 102, 1969, pp. 2939-2950.
McKeon, J. E. et al. Tetrahedron, vol. 28, 1972, pp. 227-232.
McKeon, J. E. et al., Tetrahedron, vol. 28, 1972, pp. 233-238.
Secemski, I. I. et al., Journal of the American Chemical Society, vol. 93, No. 14, 1971, pp. 3547-3550.
Henry, P. M., Journal of the American Chemical Society, vol. 93, No. 16 1971, pp. 3853-3859.
Henry, P. M., Journal of the American Chemical Society, vol. 94, No. 21, 1972, pp. 7311-7315.
Henry, P. M., Journal of the American Chemical Society, vol. 94, No. 21, 1972, pp. 7316-7322.
Pandey, R. N. et al., Canadian Journal of Chemistry, vol. 53, 1975, pp. 2223-2231.
Allen, N. P. et al., Inorganica Chimica Acta, 28, 1978, pp. 231-235.
Rotem, M. et al., Organometallics, 2, 1983, pp. 1689-1691.
Mitsudo, T. et al., J. Org. Chem., vol. 50, No. 9, 1985, pp. 1566-1568.
Mitsudo, T. et al., J. Org. Chem., vol. 52, No. 11, 1987, pp. 2230-2239.
Vinyl Polymers (Acetate), Kirk-Othmer Encyclopedia of Chemical Technology, Third Edition, vol. 23, pp. 817-847.
Crooks, G. R. et al. J. Chem. Soc. (A), 1969, pp. 2761-2766.
Cotton, F. A. et al., Chemical Communications, 1971, pp. 967-968.
Spencer, A. et al., J. C. S. Dalton, 1972, pp. 1570-1577.
Legzdins, P. et al., J. Chem. Soc. (A), 1970, pp. 3322-3326.
Gareev, G. A. et al., Zhurnal Organicheskoi Khimii, vol. 13, No. 3, 1977, pp. 606-607.
Robinson, S. D. et al., J. C. S. Dalton, 1973, pp. 1912-1920.
Fouda, S. A. et al., Inorganic Chemistry, vol. 17, No. 11, 1978, pp. 3213-3220.
Spencer, A., Inorg. Nucl. Chem. Letters, vol. 12, 1976, pp. 661-663.
Komiya, S. et al., Chemistry Letters, 1987, pp. 1287-1290.
Leonard, Edward C., Vinyl and Diene Monomers, Part 1, Higher Polymers, vol. XXIV, Wiley Interscience, pp. 331-334.

Affiliated with

Also associated with

Rating

Transvinylation reaction does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Transvinylation reaction, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Transvinylation reaction will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-1997558