Production of carboxylic acids and esters

Details Production of carboxylic acids and esters Production of carboxylic acids and esters

1982-01-04

1986-09-16

Garner, Vivian

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

560241, 562517, 562519, 585640, 585733, C07C 120, C07C 5112, C07C 6736

Patent

active

046123873

ABSTRACT:
A method for making monocarboxylic acids and esters comprising contacting carbon monoxide and a monohydric alcohol containing 1 to 4 carbon atoms in the presence of a crystalline aluminosilicate zeolite having a silica to alumina ratio at least about 6 and a constraint index within the approximate range of 1 to 12 under a pressure of at least one atmosphere. Also coproduced are hydrocarbons, particularly ethylene and "gasoline".

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CA 93:45920m.
J. B. Nagy et al. in J. Mol. Cat., 5 (1979), 393-397.
C. D. Chang and A. J. Silvestri in J. Cat., 45 (1977), 249-259.
C. D. Chang et al. in J. Catal. 56 (1979), 169-173.

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