Cerium regeneration aid for ruthenium hydrogenation catalyst

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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252462, 260583K, 260690, C07C 8512

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active

041728491

ABSTRACT:
In a ruthenium hydrogenation catalyst cerium moderates loss in catalytic activity and the physical degradation of the catalyst. In one embodiment, upon repeated regenerations during the catalytic hydrogenation of branched chain olefinically unsaturated aliphatic dinitriles, a ruthenium-cerium/Al.sub.2 O.sub.3 catalyst maintained a catalytic activity at higher levels through a series of hydrogenations and regenerations than did a catalyst containing only ruthenium.

REFERENCES:
patent: 3404098 (1968-10-01), Stiles
patent: 3518206 (1970-06-01), Sowards et al.
patent: 3679773 (1972-07-01), Kovach et al.
patent: 3794588 (1974-02-01), Stiles
patent: 3880929 (1975-04-01), Drake
patent: 3896173 (1975-07-01), Drake
patent: 4053515 (1977-10-01), Drake

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