Organic compounds -- part of the class 532-570 series – Organic compounds – Nitriles
Patent
1992-05-05
1993-05-04
Brust, Joseph Paul
Organic compounds -- part of the class 532-570 series
Organic compounds
Nitriles
C07C25330
Patent
active
052083632
ABSTRACT:
The present invention is a process for preparing aminoacetonitriles or ethylenediamine tetraacetonitrile comprising the steps of (a) admixing glycolonitrile with an amine having at least one primary amine group or ethylenediamine to form an intermediate amine acetonitrile reaction product, (b) admixing the reaction product of Step (a) with formaldehyde and hydrocyanic acid such that each hydrogen on an amine nitrogen is replaced by an acetonitrile group. The resulting aminoacetonitrile advantageously has all amino groups fully substituted with acetonitrile groups.
REFERENCES:
patent: 2205995 (1940-06-01), Ulrich et al.
patent: 2405966 (1946-08-01), Loder
patent: 2407645 (1946-09-01), Bersworth
patent: 2731490 (1956-01-01), Barsky
patent: 2855428 (1958-10-01), Singer et al.
patent: 2860164 (1958-11-01), Kroll et al.
patent: 2890238 (1959-06-01), Sexton
patent: 3424783 (1969-01-01), Harper et al.
patent: 3463805 (1969-07-01), Morgan et al.
patent: 3515742 (1970-06-01), Morgan et al.
patent: 3644444 (1972-02-01), Popper et al.
patent: 3679729 (1972-07-01), Daniels
patent: 3714223 (1973-01-01), Godfrey et al.
patent: 3758534 (1973-09-01), Popper et al.
patent: 3907858 (1975-09-01), Davis et al.
patent: 3925448 (1975-12-01), Tanier
patent: 3959342 (1976-05-01), Homberg et al.
patent: 3988360 (1976-10-01), Gaudette et al.
patent: 4022815 (1977-05-01), Schlecht et al.
patent: 4478759 (1984-10-01), Diatler et al.
patent: 4560516 (1985-12-01), Singer
patent: 4661614 (1987-04-01), Most et al.
patent: 4704465 (1987-11-01), Tannet et al.
patent: 4980471 (1990-12-01), Christiansen et al.
Stewart, et al., J. Chem. Soc., pp. 3281-3285, (1940), vol. 62.
Choh-Hao Li, et al., J. Chem. Soc., pp. 2596-2599, (1937), vol. 59.
Stewart, et al., J. Chem. Soc., pp. 2782-2787, (1938), vol. 60.
Crump Druce K.
Wilson David A.
Brust Joseph Paul
The Dow Chemical Company
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