Process for the preparation of trialkyl ester derivatives

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

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558 52, C07C 6934

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active

056061005

ABSTRACT:
A process for the preparation of trialkyl ester derivatives of the general formula: ##STR1## wherein X is chlorine, bromine, iodine, tosyloxy or mesyloxy and R is a C.sub.1 -C.sub.6 -alkyl group. According to this process, a trialkyl methanetricarboxylate of the general formula: ##STR2## wherein R has the meaning given above, is converted to the end product of formula I with a disubstituted ethane of the general formula:

REFERENCES:
H. Padgett et al., Jr. Org. Chem., vol. 44, No. 20, (1979), pp. 3492 to 3496.
H. Lund & A. Voigt in Organic Syntheses, Collect. vol. II, Wiley, New York (1946), p. 594.

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