Method of controlling the polymerization of acrylates

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Halogen or compound containing same

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502224, B01J 27138

Patent

active

055785441

ABSTRACT:
The present invention relates to a method of controlling the polymerization of acrylates using a catalyst which is selected from at least one of zinc, cadmium, or mercury halides in combination with free iodine to give acrylate polymers having narrow molecular weight distributions, via group transfer polymerization.

REFERENCES:
patent: 3332910 (1967-07-01), Mudde
patent: 3868317 (1975-02-01), Itoh et al.
patent: 4190521 (1980-02-01), Antos
patent: 4414372 (1983-11-01), Farnham
patent: 4417034 (1983-11-01), Webster
patent: 4508880 (1985-04-01), Webster
patent: 4766103 (1988-08-01), Cobb
Macromolecules 1984, 17, 1415-1417.

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