Soluble anionic polymerization initiators and method of preparin

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Organic compound containing

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502150, 502172, 502200, 540450, 540470, 540477, 540484, 544358, 546184, 548400, 526180, 526204, 526217, 526220, 25218212, C08F 408, C07D29500, C07D48708

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055785425

ABSTRACT:
An acyclic alkane soluble anionic polymerization initiator includes a mixture of from about 90 to about 10 parts by weight of a lithio amine having the general formula A.sub.1 Li and from about 10 to about 90 parts by weight of at least one other lithio amine having the general formula A.sub.2 Li. A.sub.1 and A.sub.2 are selected from the dialkyl, alkyl, cycloalkyl and dicycloalkyl amine radicals and cyclic amine radicals. There is also provided a method of forming a mixture of anionic polymerization initiators, a functionalized polymer and a method of forming a functionalized polymer.

REFERENCES:
patent: 2849432 (1958-08-01), Kibler et al.
patent: 3290277 (1966-12-01), Anderson et al.
patent: 3317918 (1967-05-01), Foster
patent: 3426006 (1969-02-01), N utzel et al.
patent: 4015061 (1977-03-01), Schulz et al.
patent: 4316001 (1982-02-01), Boileau et al.
patent: 4478953 (1984-10-01), Yuki et al.
patent: 4931376 (1990-06-01), Ikematsu et al.
patent: 4935471 (1990-06-01), Halasa et al.
patent: 4978754 (1990-12-01), Ibi et al.
patent: 5115035 (1992-05-01), Shiraki et al.
patent: 5149457 (1992-09-01), Smith
patent: 5173209 (1992-12-01), Smith, Jr. et al.
Riddick et al., Organic Solvents (3rd ed.) Wiley-Inter-Science, N.Y., 52-3 (1970).
Anionic Polymerization Initiated by Diethylamide In Organic Solvents, Angood et al, Journal of Polymer Science, vol. 11, pp. 2777-2791 (1973).
Anionic Polymerization Initiators Containing Protected Functional Groups, Schulz et al, Journal of Polymer Science, vol. 15, pp. 2401-2410 (1977).
Anionic Polymerization, Cheng, American Chemical Society Symposium Series 166, American Chemical Society, pp. 513-527 (1981).
Copolymerization of Butadiene and Styrene by Initiation with Aklyllithium and Alkali Metal tert-Butoxides, Wofford and Hsieh, J. of Polymer Science, vol. 7, 461-469 (1969).
Butadiene-Styrene Copolymerization Initiated by n-BuLi/THF/t-AmOK, Lehong et al; J. of Applied Polymer Science; vol. 44, 1499-1505 (1992).
The Microstructure of Butadiene and Styrene Copolymers Synthesized with n-BuLi/THF/t-AmOK, Lehong et al; J. of Applied Polymer Science, vol. 44, 1507-1511 (1992).

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