Adhesive bonding and miscellaneous chemical manufacture – Methods – Surface bonding and/or assembly therefor
Patent
1996-12-31
2000-10-24
Knable, Geoffrey L.
Adhesive bonding and miscellaneous chemical manufacture
Methods
Surface bonding and/or assembly therefor
152510, B60C 514, B29D 3008
Patent
active
061361232
DESCRIPTION:
BRIEF SUMMARY
TECHNICAL FIELD
The present invention relates to a process for producing a pneumatic tire using a thermoplastic film for an inner liner of the tire which lightens the weight of the tire, without detracting from the retention of air in the tire and reduces a defect rate of the tire and improves the working efficiency during the production of tire.
BACKGROUND ART
Reduction of fuel consumption is one of the major technical issues in automobiles. As one of the means for this issue, strong demands have been made for reduction of the weight of pneumatic tires. In this regard, an inner liner layer or other air permeation preventive layer comprised of a halogenated butyl rubber or other rubber having low air permeability is conventionally provided at the inner surface of the pneumatic tire to hold the air pressure in the tire constant. However, a halogenated butyl rubber has a large hysteresis loss, and therefore, after vulcanization of the tire, when rippling is caused in the rubber of the inner surface of the carcass layer and the inner liner layer in the spaces between the carcass cords, the inner liner layer deforms along with deformation of the carcass layer. Thus, there is the problem of an increase in the rolling resistance. Therefore, in general, a rubber sheet called a "tie rubber" having a small hysteresis loss has been inserted between the inner liner layer (e.g., halogenated butyl rubber) and rubber of the inner surface of the carcass layer for joining the both layers. Accordingly, in addition to the thickness of the inner liner layer of the halogenated butyl rubber, the thickness of the tie rubber is added and the overall layer becomes a thickness of more than 1 mm (1,000 .mu.m). As a result, this has become a factor increasing the weight of the final tire.
Techniques have been proposed for using various materials in place of the butyl rubber or other low air permeability rubber as an air permeation preventive layer, such as the liner layer, of a pneumatic tire. For example, Japanese Unexamined Patent Publication (Kokai) No. 6-40207 proposes the formation of a thin film from an air permeation preventive layer at the inside of the tire by laminating a low air permeability layer comprised of a polyvinylidene chloride film or ethylenevinyl alcohol copolymer film and an adhesive layer comprised of a polyolefinic film, aliphatic polyamide film, or polyurethane film and laminating that thin film on the inner surface of a green tire comprised of unvulcanized rubber so that the adhesive layer contacts the carcass layer, then vulcanizing and molding the green tire. By using this multilayer film for the air permeation preventive layer, it is possible to reduce the thickness of the air permeation preventive layer from the past and possible to reduce the weight of the tire without detracting from the retention of the air pressure.
However, while a pneumatic tire using such a thermoplastic film as disclosed in Japanese Unexamined Patent Publication (Kokai) No. 6-40207 for the inner liner is superior in performance, it has problems in terms of the working efficiency and manufacturing cost and also problems in the occurrence of wrinkles, blistering, etc. at the time of adhesion of the thermoplastic film which has resulted in defective tires. Further, one method of adhering the thermoplastic film is to first manufacture the green tire, then adhere a strip of film to the inner surface or wrap the strip of film and carcass together around the molding drum and then inflate them. In these methods, however, when the adhesive strength at the splice portion of the film is poor, the splice portion (i.e., joined portion) will open up (splice opening) at the time of vulcanization of the tire or the work will be troublesome when manufacturing the green tire and therefore the work efficiency will be poor.
SUMMARY OF THE INVENTION
Accordingly, the object of the present invention is to provide a process for producing a pneumatic tire which eliminates the problems in a pneumatic tire using the above thermoplastic film as the
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Kirk-Othmer, Encyclopedia of Chemical Technology, 4th ed., vol. 1, "Adhesives", pp. 445-466, 1991.
English Language Abstract for JP 06-184,327; Jul. 5, 1994.
Kaido Hiroyuki
Kawaguchi Gou
Kuroda Noriaki
Watanabe Jiro
Yamakawa Kazuto
Knable Geoffrey L.
The Yokohama Rubber Co. Ltd.
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