Organopolysiloxanes, modified with acrylate groups in the presen

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From silicon reactant having at least one...

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528 26, 522 99, C08G 7708, C08G 7720

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active

055525067

ABSTRACT:
Organopolysiloxanes, which terminally, laterally or both have at least one group of the formula ##STR1## well as at least one acrylate group, linked over a bridge element to this group, is obtained by hydrosilylation of organopolysiloxanes with at least one SiH group by compounds, which have at least two acrylate groups, in equimolar amounts at a temperature of 60.degree. to 130.degree. C. in presence of rhodium catalysts. The rhodium catalysts cause a 1,2 addition to take place during the addition reaction between polyacrylates and hydrogen siloxanes.

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Bruce J. Kokko, Silicone Acrylates Through The . . . , Journal of Applied Polymer Science, vol. 47, 1309-1314, (1993).

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