Process for the electrolytic deposition of metals

Chemistry: electrical and wave energy – Processes and products – Electrostatic field or electrical discharge

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204114, 204120, C25C 122, C25C 114, C25C 118

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active

054645077

ABSTRACT:
A process for the electrolytic recovery of metals from solutions containing metal ions and fluorides and/or anionic flurocomplexes in diaphragmless cells wherein the deposition of the metals at the cathodes and the oxygen evolution at the anodes is effected, the improvement comprising the use of insoluble anodes made of sintered powders of doped tin dioxide optionally provided with coating of zirconyl phosphate and metal oxides which prevents the deposition of metal oxides on the anode surface and catalyze the oxygen evolution reaction.

REFERENCES:
patent: 3772168 (1973-11-01), Dillenberg
patent: 4146438 (1979-03-01), De Nora et al.
patent: 4720334 (1988-01-01), DuBois et al.
patent: 5207877 (1993-05-01), Weinberg et al.
Hibbert et al., Dictionary of Electrochemistry, "Electroplating", Second Edition, p. 127, 1984.

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