Process for the preparation of alkyl tert-alkyl ethers

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568698, C07C 4105

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active

046057870

ABSTRACT:
Process for the preparation of alkyl tert-alkyl ethers which comprises reacting a primary alcohol with an olefin having a double bond on a tertiary carbon atom in the presence of an acidic zeolite catalyst. Removal of any excess alcohol from the reaction product is accomplished by passing the reaction product through a bed of small pore zeolite.

REFERENCES:
patent: 3170000 (1965-02-01), Verdol
patent: 3726942 (1973-04-01), Louder
patent: 3728408 (1973-04-01), Tobias
patent: 3966586 (1976-01-01), Owen et al.
Hersh, Molecular Sieves, Reinhold Publishing, New York, pp. 29-30, 44-45, 78-79.
Venuto, Chem. Tech., Apr. 1, 1971, pp. 215-224.

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