Preparation of substituted aromatic compounds

Details Preparation of substituted aromatic compounds Preparation of substituted aromatic compounds

1977-01-24

1980-01-08

Lone, Werren B.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

260781, 26034611, 568732, 568735, 568744, C07C 3902, C07C 3912, C07D30700

Patent

active

041829158

ABSTRACT:
Process for the preparation of nucleophilically ring-substituted aromatic compounds from an aromatic-thallium (III) metallate is provided in which the aromatic-thallium (III) metallate is contacted with a source of the nucleophile to form the desired substituted aromatic compound, which may be recovered from the reaction mixture as by distillation. Exemplary processes include the preparation of aniline and phenol from benzene.

REFERENCES:
McKilop et al., "Advances in Organometallic Chemistry", vol. 11, pp. 147-201, esp. pp. 169-177.
Taylor et al., "J. Org. Chem.", vol. 40, No. 16, 1975, pp. 2351-2355.
Taylor et al., "JACS", 92:7, Apr. 8, 1970, pp. 2175-2177.
Taylor et al., "JACS", 92:11, Jun. 3, 1970, pp. 3520-3522.

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