Process for the selective hydrogenation of epoxyalkenes to epoxy

Details Process for the selective hydrogenation of epoxyalkenes to epoxy Process for the selective hydrogenation of epoxyalkenes to epoxy

1994-06-17

1995-02-21

Evans, Joseph E.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

502166, 549555, 568483, 568907, C07D30100, C07D30304, C07D30322

Patent

active

053917731

ABSTRACT:
Disclosed is a process for the homogeneous, catalytic hydrogenation of epoxyalkenes and epoxycycloalkenes, especially conjugated .gamma.,.delta.-epoxyalkenes and .gamma.,.delta.-epoxycycloalkenes, to the corresponding epoxyalkanes and epoxycycloalkanes using a solution of a complex rhodium catalyst whereby the olefinic unsaturation is hydrogenated without significant hydrogenolysis of the conjugated epoxy group.

REFERENCES:
patent: 3005832 (1961-10-01), Payne et al.
patent: 3336241 (1967-08-01), Shokal
patent: 5117013 (1992-05-01), Falling

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