Oxygen alkylation of phenol-containing hydrocarbonaceous streams

Mineral oils: processes and products – Refining – Organic acid or phenol contaminant removal

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208 8R, 208 48R, 568630, C10G 1908, C07C 4100

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active

042773261

ABSTRACT:
Process for improving properties of phenol-containing hydrocarbonaceous streams such as a coal liquid by contacting stream with (a) a multivalent metal composition selected from the group consisting of oxides and/or hydroxides of multivalent metals capable of forming hydroxy metal phenates with the phenols of the stream; and (b) one or more alkylating agents represented by the formula RX where R is a C.sub.1 to C.sub.18 group selected from the group consisting of alkyl, allyl, cycloalkyl, haloalkyl, benzyl, and arylalkyl, provided X is located on the alkyl portions of the alkylating agent and X is sulfate or a halide.

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Gardner et al. "Magnesium Hydroxide in Petroleum Industry" Ind. Eng. Chem. 24, 1141-1146, (1932).
Blom et al. Fuel 36, 135-153, (1957).
Yohe et al. J. Am. Chem. Soc. 69, 2644-2648, (1947).

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