Process for the preparation of organopolysilazanes and of organo

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From silicon reactant having at least one...

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528 23, 528 28, 528 32, 525474, 501 92, 501154, C08G 7706

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active

046893822

ABSTRACT:
The present invention relates to a process for the treatment of polysilazane in a homogeneous phase with a catalytically effective quantity of an acid catalyst selected from HClO.sub.4 and CF.sub.3 SO.sub.3 H. The polysilazane is preferably selected from the group consisting of organopolysilazane, organopoly(disilyl)silazane and mixtures thereof. The organic radicals bonded to the silicon atoms are preferably saturated or aromatic hydrocarbon radicals and the silicon atoms of the polysilazane are substantially free from any hydrogen atom bonded directly to the silicon atoms.
The polysilazanes treated in this manner have good thermal behavior and, are particularly useful as precursors of ceramic products.

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patent: 3892583 (1975-07-01), Winter et al.
patent: 4097294 (1978-06-01), Rice et al.
patent: 4314956 (1982-02-01), Baney et al.
patent: 4340619 (1982-07-01), Gaul, Jr.
patent: 4395460 (1983-07-01), Gaul
patent: 4404153 (1983-09-01), Gaul, Jr.
patent: 4482669 (1984-11-01), Seyferth et al.

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