Process for preparing para-aminophenol

Chemistry: electrical and wave energy – Processes and products

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C25B 300

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active

045840709

ABSTRACT:
Disclosed is a method of preparing para-aminophenol by the electrolytic reduction of nitrobenzene in an acidic, aqueous reaction medium including a trialkylamine-N-oxide surfactant, such as dimethyldodecylamine-N-oxide, by electrolytic reduction at a cathode comprised of an amalgamated metal, and by electrolytic reduction under essentially anerobic or oxygen-free conditions in the catholyte.

REFERENCES:
patent: 3338806 (1963-10-01), Harwood
patent: 3475299 (1969-10-01), Slager
patent: 3645864 (1972-02-01), Lawson
patent: 4264529 (1981-04-01), Dunn
patent: 4307249 (1981-12-01), Derrenbacker
patent: 4396474 (1983-08-01), Astruc et al.
patent: 4415753 (1983-11-01), Caskey et al.
Journal of Applied Electrochemistry, 10 (1980), 567-573.
Journal of the Electrochemical Society, 99, 289-294 (1952), Wilson et al.
I&EC Process Design and Development, 2, 72-77 (1963), Harwood et al.

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