Process for the production of chloropyridines substituted by met

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568448, C07C 4714

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active

044698968

ABSTRACT:
Chloropyridines of the formula ##STR1## wherein either R is chlorine and R' is methyl or trifluoromethyl, or R is methyl, trichloromethyl or trifluoromethyl and R' is chlorine, or R and R' are methyl, can be obtained by a novel, simple process by the addition of trichloroacetaldehyde to methacrylonitrile or .alpha.-trifluoromethacrylonitrile, 2,2-dichloropropionaldehyde, pentachloropropionaldehyde or 2,2-dichloro-3,3,3-trifluoropropionaldehyde to acrylonitrile, or 2,2-dichloropropionaldehyde to methacrylonitrile, in the presence of a catalyst, in particular copper powder or copper(I) chloride, and cyclizing the open-chain intermediate obtained.
The chloropyridines of the formula (I) are known per se and are suitable for the production of different compounds, in particular of insecticides and herbicides.

REFERENCES:
patent: 2568500 (1951-09-01), Housted et al.
Bekker et al., "Chemical Abstracts", vol. 83, (1975), p. 147,047t.

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