Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...
Patent
1993-01-04
1995-10-24
Teskin, Fred
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
Polymers from only ethylenic monomers or processes of...
526120, 526121, 526126, 526133, 526134, 526150, 526160, 526170, 502152, C08F 4643, C08F 1208
Patent
active
054611288
ABSTRACT:
There are disclosed a catalyst which comprises (A) a titanium compound having one .pi. electron-based ligand (e.g. pentamethylcyclopentadienyl group) or two same .pi. electron-based lignads and (B) an ionic compound comprising a non-coordinate anion and a cation of an element typifying the group 4 elements of the Periodic Table (e.g. triphenylcarbonium tetra(pentafluorophenyl)borate; a catalyst comprising (C) an alkylating agent (e.g. triisobutylaluminum) in addition to the components (A) and (B); and a process for producing a styrenic polymer by the use of any of the aforesaid catalysts. By using the aforementioned catalyst and process, a highly syndiotactic styrenic polymer can be efficiently produced.
REFERENCES:
patent: 5066741 (1991-11-01), Campbell, Jr.
patent: 5132380 (1992-07-01), Stevens et al.
patent: 5155080 (1992-10-01), Elder et al.
patent: 5272229 (1993-12-01), Tomotsu et al.
Concise Chem. and Tech. Dictionary, H. Bennett (ed.) Chemical Publishing Co., Inc., N.Y., N.Y., p. 1076 (1974).
Takeuchi Mizutomo
Tomotsu Norio
Idemitsu Kosan Co. Ltd.
Teskin Fred
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