Process for producing a styrenic polymer

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526120, 526121, 526126, 526133, 526134, 526150, 526160, 526170, 502152, C08F 4643, C08F 1208

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054611288

ABSTRACT:
There are disclosed a catalyst which comprises (A) a titanium compound having one .pi. electron-based ligand (e.g. pentamethylcyclopentadienyl group) or two same .pi. electron-based lignads and (B) an ionic compound comprising a non-coordinate anion and a cation of an element typifying the group 4 elements of the Periodic Table (e.g. triphenylcarbonium tetra(pentafluorophenyl)borate; a catalyst comprising (C) an alkylating agent (e.g. triisobutylaluminum) in addition to the components (A) and (B); and a process for producing a styrenic polymer by the use of any of the aforesaid catalysts. By using the aforementioned catalyst and process, a highly syndiotactic styrenic polymer can be efficiently produced.

REFERENCES:
patent: 5066741 (1991-11-01), Campbell, Jr.
patent: 5132380 (1992-07-01), Stevens et al.
patent: 5155080 (1992-10-01), Elder et al.
patent: 5272229 (1993-12-01), Tomotsu et al.
Concise Chem. and Tech. Dictionary, H. Bennett (ed.) Chemical Publishing Co., Inc., N.Y., N.Y., p. 1076 (1974).

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