Cathode materials for lithium batteries and methods for producin

Chemistry: electrical current producing apparatus – product – and – Current producing cell – elements – subcombinations and... – Electrode

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H01M 448, H01M 452

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active

057801851

ABSTRACT:
An amorphous solid solution of V.sub.2 O.sub.5, CoO.sub.2, P.sub.2 O.sub.5, MO (wherein M represents an alkaline earth metal element) and at least one lithium compound selected from the group consisting of lithium-oxygen compounds, lithium halides and lithium oxygen acid salts is formed by melting precursor materials therefore, then the melt is put into water or pressed with metal plates to quench it, and the solid solution is heat treated above its glass transition temperature, the resulting solid solution being used as a cathode material for a lithium battery, thereby obtaining the lithium battery preventing the capacity of a carbon anode from lowering and excellent in long-term cycle stability.

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Proceedings Of The Symposium On High Power, Ambient Temperature Lithium Batteries, vol. 92, No. 15, Oct. 1991, Pheonix AZ, US, pp. 113-126, D. Guyomard et al.; "Lithium Metal-Free Rechargeable LT1+SMN204/Carbon Cells".
Chemical Abstracts, vol. 115, No. 10, Sep. 9, 1991, Columbus, OH, US, Okada et al. "Manufacture Of Secondary Nonaqueous Batteries".
F. Albert Cotton and Geoffrey Wilkinson, "Advanced Inorganic Chemistry", Wiley-Interscience, 1972, p. 885.

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