Organic compounds -- part of the class 532-570 series – Organic compounds – Nitrogen attached directly or indirectly to the purine ring...
Patent
1985-05-03
1988-05-31
Jiles, Henry R.
Organic compounds -- part of the class 532-570 series
Organic compounds
Nitrogen attached directly or indirectly to the purine ring...
546113, 546116, 546193, 546194, 546281, 546291, 546296, 546297, 546299, 546306, 546316, 546321, 546250, C07D213803, C07D21382, C07D47104, C07D491048
Patent
active
047482443
ABSTRACT:
The invention relates to a process for the preparation of pyridine-2,3-dicarboxylic acid derivatives of formula ##STR1## which process comprises reacting a hydrazone of formula II ##STR2## with a maleic acid derivative of formula III ##STR3## to give a 1-amino-1,4-dihydropyridine-2,3-dicarboxylic acid derivative of formula IV ##STR4## and subsequently removing R.sub.9 R.sub.10 NH. In the above formulae, R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.9, R.sub.10 and X are as defined in claim 1. The pyridine-2,3-dicarboxylic acid derivatives of formula I are intermediates for the preparation of herbicidal compounds.
REFERENCES:
patent: 3027380 (1962-03-01), Leonard et al.
patent: 4439607 (1984-03-01), Drabb
Cochran, J. L. et al, J. Org. Chem 26, pp. 808-811 (1961).
Oakes, V. et al, J. Chem. Soc. 1956, pp. 4433-4438.
Bellus Daniel
Roloff Achim
Waldner Adrian
Bjorkman Dale A.
Ciba-Geigy Corporation
Jiles Henry R.
Mansfield Kevin T.
McC. Roberts Edward
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