Supported catalysts for addition of silicon hydrides to .alpha.,

Organic compounds -- part of the class 532-570 series – Organic compounds – Silicon containing

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C07F 710

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051264692

ABSTRACT:
The present invention is a process for the preparation of hydrolyzable .beta.-cyanoalkylsilanes. More particularly, this invention relates to the catalytic addition of hydrolyzable silicon hydrides to .alpha.,.beta.-unsaturated olefinic nitriles to form .beta.-cyanoalkylsilanes. The instant process employs a catalyst comprising a diamine and supported copper or a supported copper compound.

REFERENCES:
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patent: 2906764 (1959-09-01), Jex et al.
patent: 2971970 (1961-02-01), Bluestein
patent: 2971972 (1961-02-01), Bluestein
Rajkumar et al., Organometallics 8, 550-552, 1989.
Svoboda et al., Collection Czechoslov. Chem. Commun. 38, 3834-3836, 1973.

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