High selectivity cyanoalkylation process

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260464, 260465R, 260465D, 260465E, 260465F, 2604651, 2604654, 2604655R, C07C12000

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active

042710880

ABSTRACT:
In a cyanoalkylation process involving the reaction of a cyanoalkene compound such as acrylonitrile with a compound containing a labile hydrogen such as ethylene glycol, to form a cyanoalkylated product such as 3,3'-ethylenedioxybis(propionitrile), the conversion of the cyanoalkene is limited to about 60 to 96%, preferably 70 to 85%, whereby the formation of byproducts is reduced from that which is obtained when the conversion of the cyanoalkene is greater than about 96%.

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