Process for polymerization of olefinic monomers

Details Process for polymerization of olefinic monomers Process for polymerization of olefinic monomers

1997-07-16

1998-06-30

Schofer, Joseph L.

Synthetic resins or natural rubbers -- part of the class 520 ser

Synthetic resins

Polymers from only ethylenic monomers or processes of...

526346, 5263297, 526254, C08F 406

Patent

active

057735387

ABSTRACT:
Free radically polymerizable olefinic monomers may be polymerized by using a fluorinated alkyl sulfonyl chloride or bromide and optionally a lower valent metal compound as an initiator system. Monomers such as styrenes, (meth)acrylics, halogenated olefins and vinyl ethers may be polymerized to a variety of thermoplastics or elastomers.

REFERENCES:
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M. Asscher et al, J. Chem. Soc. (1964) pp. 4962-4971.
A. Orochov et al, J. Chem. Soc. (1969), pp. 255-259.
N. Kamigata et al, J. Chem. Soc., Perkin Trans. I (1991) pp. 627-633.
V. Percec et al, Macromolecules, vol. 28, pp. 7970-7972 (1995) and vol. 29, pp. 3665-3668 (1996).

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