Preparation of 2-cyano-3,3-dimethyl-cyclopropane-1-carboxylic ac

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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2604654, 562506, C07C12000, C07C12146, C07C12116

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043327451

ABSTRACT:
A process for the preparation of a 2-cyano-3,3-dimethyl-cyclopropane-1-carboxylic acid ester of the formula ##STR1## in which R is optionally substituted alkyl,
comprising reacting a 3-halogeno-3-cyano-2,2-dimethyl-propane-1-carboxylic acid ester of the formula ##STR2## in which X is halogen,
with a base at a temperature from about 0 to 100.degree. C. The starting esters are new and may be prepared by halogenating a compound of the formula ##STR3## and decarboxylating.

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