Photoactivated catalytic hydrosilylation of carbonyl compounds

Details Photoactivated catalytic hydrosilylation of carbonyl compounds Photoactivated catalytic hydrosilylation of carbonyl compounds

1981-07-17

1982-06-01

Shaver, Paul F.

Chemistry: electrical and wave energy

Processes and products

Processes of treating materials by wave energy

556470, C07F 718

Patent

active

043326544

ABSTRACT:
A process to form silyl ethers by contacting a carbonyl compound with an organosilicon hydride under reaction conditions in the presence of a catalyst, said catalyst being formed from a transition metal carbonyl coordination compound precursor by irradiation at an appropriate wavelength.

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Jetz G. Graham, Silicon-Transition Metal Chemistry I. Photochemical Preparation of Silyl (Transition Metal) Hydrides, 10 Inorganic Chemistry 4 (1971).
Pittman, Jr., "Photocatalysis of Hydrosilylation Using Metal Carbonyls," (Abstract of talk given at the 181st ACS National Meeting held in Atlanta, GA, Mar. 29-Apr. 3 (1981).

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