Method for synthesis of high capacity Li.sub.x Mn.sub.2 O.sub.4

Chemistry of inorganic compounds – Oxygen or compound thereof – Metal containing

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429224, C01G 4512, H01M 450

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054259320

ABSTRACT:
Lithium intercalation compounds suitable for use in high capacity secondary battery electrodes are prepared by reacting together at a temperature in the range of about 800.degree. to 900.degree. C. lithium and manganese compounds in a stoichiometric ratio resulting in a Li.sub.x Mn.sub.2 O.sub.4 compound wherein x is within the range of about 1.00 to 1.20. The resulting compound is annealed at a temperature in excess of about 800.degree. C. and cooled to at least about 500.degree. C. at the rate less than about 10.degree. C. per hour before being finally cooled to ambient working temperature. Intercalation electrodes comprising these lithiated compounds are used in secondary batteries to yield stable, extended capacities in excess of 110 AHr/Kg.

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Wickham, D. G., "Crystallographic and . . . Spinels Containing Trivalent JA-1044 Manganese", J. Phys. Chem. Solids, 1958, vol. 7, pp. 351-360.

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