Process for the preparation of polyphenylene ethers with activat

Chemistry of carbon compounds – Miscellaneous organic carbon compounds

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C08G 6700, C08G 6542

Patent

active

039882977

ABSTRACT:
There is disclosed herein an improved process for the preparation of high molecular weight polyphenylene ethers by oxidatively coupling a di-ortho substituted phenolic precursor in a reaction vessel containing oxygen and a complex catalyst formed from a copper salt and either a primary, secondary or tertiary amine wherein in the presence of an aqueous phase a quaternary ammonium salt is employed to promote the rate of reaction.

REFERENCES:
patent: 3365422 (1968-01-01), Van Dort
patent: 3549670 (1970-12-01), Spousta et al.
patent: 3733299 (1973-05-01), Cooper et al.
patent: 3787358 (1974-01-01), Nishioka et al.

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