Chemistry of inorganic compounds – Sulfur or compound thereof – Elemental sulfur
Patent
1977-06-23
1978-10-31
Thomas, Earl C.
Chemistry of inorganic compounds
Sulfur or compound thereof
Elemental sulfur
423239, 423242, 423243, 423244, 423352, 423539, 423564, C01B 1704, B01D 5334
Patent
active
041235070
ABSTRACT:
A feed gas containing one or more components selected from the class consisting of H.sub.2 S, SO.sub.2, SO.sub.3, COS, CS.sub.2, light mercaptans, and sulfur vapor is desulfurized by (a) hydrogenating and hydrolyzing essentially all non-H.sub.2 S sulfur components to H.sub.2 S, (b) oxidizing most of the H.sub.2 S in the resulting product gas to sulfur, and removing the latter by condensation, (c) oxidizing the residual H.sub.2 S to SO.sub.2, (d) absorbing essentially all the SO.sub.2 in an aqueous ammonia solution, (e) passing a portion of the SO.sub.2 -containing ammonia solution to step (a), and (f) discharging from step (d) a purified product gas essentially free of sulfur components.
A feed gas, such as a stack gas, which contains only SO.sub.2 and SO.sub.3 components to be removed therefrom, may be treated in alternative embodiments of the invention involving the passage of all or a major proportion of the feed gas directly to absorption step (d).
In all embodiments of the invention a substantial proportion of NO.sub.x components, if present in the feed gas, is also removed.
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Hartman Richard C.
Henderson Lannas S.
Thomas Earl C.
Union Oil Company of California
Wirzbicki Gregory F.
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