Process for producing 2-hydroxy-4-methyltetrahydrofuran

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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568454, 568455, 568861, 568862, C07D30720, C07C 29132

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active

056841671

ABSTRACT:
2-Hydroxy-4-methyltetrahydrofuran is prepared by reacting 2-methyl-2-propen-1-ol with hydrogen and carbon monoxide in the presence of:

REFERENCES:
Chemical Abstracts, vol. 116, No. 15, Apr. 13, 1992, AN 151552w, M. Matsumoto, et al., "Preparation of Dihydrofurans" & JP-A-03 261 776, Nov. 21, 1991.
Chemical Abstracts, vol. 103, No. 3, Jul. 22, 1985, AN 22459d, "2-Hydroxy-4-Methyl-Tetrahydropyran" & JP-A-60 019 781, Jan. 31, 1985.
Chemical Abstracts, vol. 116, No. 12, Mar. 30, 1992, AN 128646w, M. Matsumoto, "Preparation of 2-Hydroxytetrahydrofuran" & JP-A-03 261 775, Nov. 21, 1991.
Organometallics, vol. 11, pp. 3525-3533, 1992, A. Polo, et al., "Regioselective Hydroformylation of Cyclic Vinyl and Allyl Ethers with Rhodium Catalysts. Crucial Influence of the Size of the Phosphorous Cocatalyst".
Advances In Chemistry Series, vol. 230, pp. 395-418, 1992, A.A. Oswald, et al., "Electronic Effects on the Synthesis, Structure, Reactivity and Selectivity of Rhodium Hydroformylation Catalysts".
J. Prakt. Chem, vol. 314, pp. 840-850, 1972, C. Botteghi, et al., "Synthese von Optisch Aktiven und Racemischen 3-Alkyl-Tetrahydrofuranen".
Botteghi, Gazzetta Chimica Italiana, vol. 105, pp. 233-245 (1975).
Fell et al., Chemiker-Zeitung, vol. 101 (7/8), pp. 343-350 (1977).

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