Process for the polymerization of vinyl chloride in the presence

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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260 23AR, 260 285D, 526 74, 526200, 526214, 526218, 526221, 5262305, 526273, 526317, C08F 3004, C08F23004

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active

041466985

ABSTRACT:
Polymerization of vinyl chloride monomer, by either suspension or emulsion polymerization, optionally in the presence of a monoethylenically unsaturated comonomer, is carried out in the presence of a mixture of calcium and zinc acrylate. The presence of the calcium and zinc acrylate yields a more thermally stable product and reduces the amount of polymer scale formation during polymerization. A further improvement in thermal stability is achieved by conducting the polymerization with the added presence of an epoxy compound containing a reactive vinyl or allyl group.

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Platzer, "Adv. in Chem. Series #85" pp. 72 & 81 ACS.

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